@article {1707,
	title = { MALDI-TOF, C-13 NMR and FTIR analysis of the cross-linking reaction of condensed tannins by triethyl phosphate },
	journal = { INDUSTRIAL CROPS AND PRODUCTS },
	volume = {95},
	year = {2017},
	pages = {621-631},
	abstract = {<p>Reaction of condensation and cross-linking of catechin monomer as a model of condensed (flavonoid) tannin extracts and of mimosa tannin itself, as well as of resorcinol with triethyl phosphate (TEP) have been investigated. FTIR, solid state CP-MAS C-13 NMR, P-31 NMR and MALDI-ToF spectroscopy studies revealed that reaction occurs mainly on the C3 of the flavonoid heterocycle ring and on the aromatic C4\&$\#$39; and C5\&$\#$39; carbons of the flavonoids B-ring, while TEP does not appear to react on the A-ring. A difference in the relative proportions of these two reaction sites for tannin and catechin has been noticed. The reactions appear to be dependent on the temperature. According to the thermogravimetric analysis, materials obtained from the reaction of tannin with TEP showed high thermal stability.</p>},
	author = {M.C. BASSO and A. PIZZI and J.P. MARIS and L. DELMOTTE and B. COLIN and Y. ROGAUME}
}
